There's a public RFC, but it's by no means usable as a bitstream spec.
There's an official text document describing the bitstream format (several hundreds pages), but it's under NDA.
We use it at work, and getting an updated version is far more trouble than downloading a file on a public server.
The document in itself is nearly worthless, though, as it's far from complete. In the end, you still need to dig into libvpx to understand how things work.
The bitstream spec is definitely public.